Process for stabilizing polyamides

ABSTRACT

Suitable compounds for stabilizing polyamides against oxidation and thermal degradation are bis-ureas and bis(acid amides) based on 2,6-di-t-butylphenol-butylamine said compounds having the general formula:

RELATED APPLICATION

This application is a division of our copending application Ser. No. 444,414, filed Feb. 21, 1974.

This invention relates to a process for stabilizing polyamides against oxidation and thermal degradation.

It is known to stabilize polyamides against the action of heat and air by adding, say, phosphites, complex copper/alkali metal halide compositions, phenolic compounds or aromatic amines.

None of these stabilizers gives perfectly satisfactory results when incorporated in polyamides.

For example, copper salt/halide system lose their stabilizing activity completely in the presence of certain pigments such as cadmium pigments or SACHTOLITH (registered trade mark). Other stabilizers, for example the p-phenylene diamine derivatives cause discoloration and are physiologically unsatisfactory. Stabilizers based on kryptophenol are either too volatile for incorporation into the polyamide melt, as in the case of 2.6-di-t-butylphenol for example, or they become discolored, as in the case of 2,2'-methylene-bis-(4-methyl-6-t-butylphenol) for example, or they have an inadequate stabilizing action, as for example 1,3,5 -trimethyl-2,4,6-tri-(3',5'-di-t-butyl-4'-hydroxybenzyl)-benzene and the β-(3,5,-di-t-butyl-4-hydroxyphenyl)-propionate of pentaerythritol.

We have now found that, surprisingly, an improvement in the stabilizing action is achieved, without discoloration of the polyamide matrix, particularly in the presence of pigments, if the stabilizers used are compounds of the general formula ##SPC2##

In the formula, the symbol Y has the following meanings: ##EQU1## is a residual radical derived from aliphatic, aromatic or aromatic-aliphatic diisocyanates and ##EQU2## is the acyl radical of an aliphatic or aromatic dicarboxylic acid.

Depending on the meanings of the radical Y, the compounds to be used in the present invention may be divided into the following groups: ##SPC3##

Specific examples of the various compounds suitable for stabilizing polyamides according to the present invention are: ##SPC4## ##SPC5##

The compounds to be used in the invention are derived from 2,6-di-t-butylphenyl-butylamine,

The compounds to be used in the present invention may be prepared by methods known in the art to which no claim is made herein, for example according to the following scheme: ##SPC6## ##SPC7##

Bis(acid amides) VI

bis-ureas V

The amount of stabilizer used is usually from 0.01 to 2% and preferably from 0.1 to 1%, by weight of solid polymer. The stabilizer may be added to the polyamide-forming monomers prior to polymerization or to the mixture during polymerization, or they may be incorporated into the finished polyamide after polymerization. Suitable processes are those usually employed for this purpose, as described for example in Kunststoff-Handbuch, Vol. VI, Polyamide, Edited by R. Vieweg and A. Muller, published by Karl Hanser Verlag, Munich, 1966. The stabilizing action extends over all polyamides and copolyamides and polyamide mixtures produced from the well-known polyamide-forming compounds such as lactams, diamines and dicarboxylic acids and aminocarboxylic acids. Examples of polyamide-forming lactams are pyrrolidone, caprolactam, capryllactam, enantholactam, aminoundecanolactam and lauroyllactam, which may be polymerized by cationic mechanisms either alone or in admixture with each other. Polycondensates of diamines and dicarboxylic acids are for example those producible from aliphatic dicarboxylic acids of from 4 to 18 carbon atoms and diamines of from 4 to 18 carbon atoms, particularly nylon 6,6 and nylon 6,10. There are obtained polyamides which are free from discoloration and which show greatly improved stability of their properties over the use of conventional phenolic stabilizers even when subjected to high thermal stresses and strong oxidizing attacks. The stabilizing action applies both to polyamides intended for the manufacture of shaped articles and to those intended for the preparation of fibers and filaments. The stabilizers of the invention are particularly suitable for use in colored polyamides, since the color values are not impaired thereby. This is particularly applicable to polyamides containing pigments. It is of no detriment when the polyamides also contain conventional fillers, e.g. glass fibers, other polymers, lubricants, crystallization accelerators and other conventional additives and other stabilizers.

The following Examples illustrate the above method of polyamide stabilization and the activity of the stabilizers used. The parts are by weight. The percentages are by weight, based on the polymer product stabilized. The characteristic mechanical property taken as a measure of the aging properties (thermal resistance) was the perforated notched impact resistance, which was measured on standard specimens according to German Standard DIN 53,453. A hole having a diameter of 3 mm was drilled in the center of the said specimens measuring 4 × 6 × 50 mm and the specimens were stored in air for 30 days at 140°C. Tests were carried out after 3, 10, 20 and 30 days, each test consisting of the determination of the perforated notched impact resistance on ten specimens, as described in "Kunststoffe" 57 (1967), pp. 825 to 828.

EXAMPLE 1

200 parts of polycaprolactam granules having a K value of 72 (1% in conc. sulfuric acid) are mechanically mixed with 1 part of the stabilizer compound listed in Table 1, and the mixture is melted in a twin-shaft kneader at 270°C and extruded, the residence time of the mixture in the kneader being 5 minutes. The extrudate is granulated, dried and converted to standard specimens according to DIN 53,453 by injection molding. The molecular weight corresponds to that of the starting polycaprolactam within the limits of error. The color of the specimens was assessed visually and the perforated notched impact resistance was determined. The results are listed in Table 1 below.

EXAMPLE 2

Example 1 is repeated using 200 parts of polycaprolactam granules having a K value of 72 and 1 part each of the stabilizer compound and pigment listed in Table 2 below. The results are listed in Table 2.

EXAMPLE 3

Example 2 is repeated using 200 parts of polyhexamethylene adipamide granules having a K value of 72 (1% w/w in conc. H₂ SO₄) in place of polycaprolactam granules. The results are listed in Table 3 below.

                                      TABLE 1                                      __________________________________________________________________________     Stabilizer                         Color Impact resistance (notched,                                                    perforated) (cmkg/cm.sup.2)                                                    after                                                                          O   3   10  20  30                    __________________________________________________________________________                                                              days                  none                               colorless                                                                            60  1.9 1.0 0.9 0.9                   CH.sub.3                                                                       |                         as starting                                 CH.sub.2 --CH.sub.2 --CH--NH--C--(CH.sub.2).sub.14 --CH.sub.3                                                     polyamide                                                                            61.5                                                                               43.7                                                                               30.8                                                                               8.5 1.8                   ∥                                                                     C--NH--CH--CH.sub.2 --CH.sub.2     "     73.7                                                                               74.0                                                                               30.0                                                                               2.7 1.8                   ∥|                                                           OCH.sub.3                                                                      CH.sub.2 --CH.sub.2 --CH--O--C--(CH.sub.2).sub.14 --CH.sub.3                                                      "     60.1                                                                               40.8                                                                               28.8                                                                               6.0 1.5                   |∥                                                           CH.sub.3 O                                                                     O                                                                              ∥                                                                     CH.sub.2 --CH.sub.2 --CH--NH--C--NH--(CH.sub.2).sub.6 --                                                          "     65.0                                                                               55.0                                                                               45.9                                                                               14.3                                                                               3.0                   |                                                                     CH.sub.3                                                                       2                                                                              O                                                                               ∥                                                                    CH.sub.2 NH--C--NH--CH--CH.sub.2 --CH.sub.2                                                                       "     60.3                                                                               40.1                                                                               20.0                                                                               8.5 1.8                   |                                                                     CH.sub.3                                                                       OCH.sub.3                                                                      ∥|                                                           NH--C--NH--CH--CH.sub.2 --CH.sub.2                                             NH--C--NH--CH--CH.sub.2 --CH.sub.2                                             ∥|                                                           OCH.sub.3                                                                                                         as starting                                                                          86.6                                                                               69.0                                                                               47.1                                                                               13.8                                                                               3.0                                                      polyamide                                   NH--CO--NH--CH--CH.sub.2 --CH.sub.2                                            |                                                                     CH.sub.3                                                                       OO                                                                             ∥∥                                                           CH.sub.2 --CH.sub.2 --CH--NH--CC--NH--CH--CH.sub.2                                                                "     60.0                                                                               55.0                                                                               20.8                                                                               6.5 0.8                   ||                                                           CH.sub.3 CH.sub.3                                                              OO                                                                             ∥∥                                                           CH.sub.2 --CH.sub.2 --CH--NH--C--(CH.sub.2).sub.8 --C--NH--CH--CH.sub.3                                           "     61.6                                                                               56.0                                                                               43.8                                                                               12.0                                                                               2.0                   ||                                                           CH.sub.3 CH.sub.2                                                              |                                                                     CH.sub.2                                                                       __________________________________________________________________________

                                      table 2                                      __________________________________________________________________________     stabilization of pigmented nylon 6 (Example 2)                                 Stabilizer                    Pigment                                                                               Color Impact resistance (notched,                                                    perforated) (cmkg/cm.sup.2)                                                    after                                                                          0  3   10  20  30                   __________________________________________________________________________                                                               days                 ∥                                                                     CH.sub.2 --CH.sub.2 --CH--NH--C--NH--(CH.sub.2).sub.6 --                                                     Cadmium                                                                               lemon 71.2                                                                              64.2                                                                               58.8                                                                               16.0                                                                               2.6                  |                    yellow 6 GN                                                                           yellow                                    CH.sub.3                                                                       2                                                                              "                             Cadmium                                                                               cherry red                                                                           68.0                                                                              53.5                                                                               45.8                                                                               10.3                                                                               1.8                                                red BBS                                          Cu complex of ethanolamine diacetic                                                                          Cadmium                                                                               dirty 46.6                                                                              1.8 1.1 0.9 0.8                  acid + KBr                    yellow 6 GN                                                                           yellow                                    "                             Cadmium red                                                                           dark red                                                                             20.2                                                                              3.4 1.1 0.9 0.9                                                BBS                                              __________________________________________________________________________

                                      table 3                                      __________________________________________________________________________     stabilization of nylon 6.6 (Example 3)                                         Stabilizer                    Pigment                                                                              Color Impact resistance (notched,                                                    perforated) (cmkg/cm.sup.2)                                                    after                                                                          0   3   10  20  30                   __________________________________________________________________________                                                               days                 none                          none  pale  68.0                                                                               2.2 1.0 0.8 0.8                  ∠                                                                        ∥                                                                     CH.sub.2 --CH.sub.2 --CH--NH--C--NH--(CH.sub.2).sub.6 --                                                     none  as starting                                |                                                                     CH.sub.3 2                          polyamide                                                                            67  55  40  10.3                                                                               4.5                  Cu complex of ethanolamine diacetic acid + KBr                                                               Sachtolith                                                                           pale  67.0                                                                               52.3                                                                               38.5                                                                               9.8 2.0                                                HD                                                                             none  slithtly                                                                       darker than                                                                          62  50  48  30  15                                                       starting                                                                       polyamide                                  "                             Sachtolith                                                                           pale gray                                                                            26.2                                                                               1.7 0.9 0.8 0.8                                                HD                                               __________________________________________________________________________ 

We claim:
 1. A process for stabilizing polyamides against oxidation and thermal degradation, which comprises adding thereto a stabilizing compound of the formula: ##SPC8##in which Y denotes ##EQU3## where R² is a radical derived from aliphatic, aromatic or aromatic/aliphatic diisocyanates and ##EQU4## is the diacyl radical of an aliphatic or aromatic dicarboxylic acid.
 2. A process as claimed in claim 1, wherein the stabilizer compound is used in amounts of from 0.01 to 2% by weight of the polyamide.
 3. A process as claimed in claim 2 wherein said amount is in the range of 0.1 to 1%.
 4. A process as claimed in claim 1 wherein said stabilizing compound is a bis-urea of the formula ##SPC9##wherein R² denotes an alkylene group, ##SPC10##
 5. A process as claimed in claim 1 wherein R² denotes an alkylene group, ##SPC11##and in which R³ denotes an alkylene group or a phenylene group or ##EQU5##
 6. A process as claimed in claim 1 wherein said polyamide is a polylactam of pyrrolidone, caprolactam, capryllactam, enantholactam, aminoundecanolactam, lauroyllactam or mixtures therof.
 7. A process as claimed in claim 1 wherein said polyamide is a polyamide polycondensate of an aliphatic dicarboxylic acid of 4 to 18 carbon atoms and a diamine of 4 to 18 carbon atoms.
 8. A process as claimed in claim 1 wherein said polyamide is nylon-6,6 or nylon-6,10.
 9. A process for stabilizing polyamides against oxidation and thermal degradation, which comprises adding thereto a stabilizing compound of the formula: ##SPC12##in which R³ denotes an alkylene group or a phenylene group or ##EQU6##
 10. A process as claimed in claim 9, wherein the stabilizer compound is used in amounts of from 0.01 to 2% by weight of the polyamide. 